Abstract
The hexamolybdate cluster has been functionalized with fluorine-containing aromatic amine by the DCC ( N, N′-dicyclohexylcarbodiimide) dehydrating protocol and two novel mono-functionalized arylimido derivatives of hexamolybdates bearing the electron-withdrawing trifluoromethyl group and trifluoromethoxy group, (Bu 4N) 2[Mo 6O 18(≡NAr)] (Ar = o-CF 3C 6H 4) 1 and (Bu 4N) 2[Mo 6O 18(≡NAr)] (Ar = p-OCF 3C 6H 4) 2 have been synthesized by improved method. Complete assignments were achieved for the title compounds by elemental analysis, IR, 1H NMR, UV/visible and single-crystal X-ray diffraction analyses. The preliminary herbicidal activity test indicated that they have some herbicidal activities.
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