Abstract
Abstract The metal-complex host of a clathrate compound [Cd3{NH(CH3)2(CH2)3NH2}(CN)7]·C6H5F has a layered structure like a clay consisting of the linkage of tetrahedral Cd(CN)4 and Cd(CN)3(NC), and octahedral Cd(NC)5[NH2(CH2)3NH(CH3)2) coordination polyhedra. The host of another clathrate [Cd3(CN)7]·{NH(CH3)2(CH2)3NH2}·(CH2ClCH2Cl) has a three-dimensional structure like a zeolite comprised of the linkage of tetrahedral Cd(CN)4 and Cd(CN)3(NC), and octahedral Cd(NC)6 coordination polyhedra; the 3-(dimethylammonio)propylamine is accommodated as a cationic guest in the cavity formed in the host structure.
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