Abstract
Abstract By the reaction of 4,4′,4″-benzene-1,3,5-triyl-tribenzoate and magnesium nitrate in a mixture of DMA/H2O, a 2D coordination network was solvothermally synthesized. When an auxiliary ligand of acetate was introduced into the reaction system for the 2D complex, a 3D metal–organic framework was successfully obtained. The layered structure features a linear Mg3 cluster as node which is terminated by four coordinated DMA molecules. However, the DMA molecules were substituted by acetate with stronger coordination ability, resulting in an infinite Mg(COO)2 chain. Then a 3D architecture was finally formed. These two compounds also exhibit strong solid fluorescent emissions.
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