Abstract
Symmetrical chloride-functionalized Anderson type POM afterwards used as a building block for onward POM post-functionalization with organic pyrene compounds and two novel organic–inorganic hybrid pyrene-POM compounds were designed, synthesized, and fully characterized. Photophysical and electrochemical properties of these compounds were investigated. Organic-inorganic hybrids retained the unique photophysical properties of their precursor pyrene compounds. Additionally, functionalization of inorganic POM moiety with organic bis-pyrene compound influenced the redox properties of the Mn-Anderson core.
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