Abstract
The precursors bis[ N-(alkyl)benzimidazoliumylmethyl]durene halide ( 1a: alkyl = C 2H 5, halide = Br −; 1b: alkyl = n-C 4H 9, halide = Cl −; durene = 1,2,4,5-tetramethylbenzene) and their two new NHC silver(I) complexes [Durene(CH 2BimyEtAgBr) 2] ( 2a) and [Durene(CH 2Bimy n BuAgCl) 2] ( 2b) (Bimy = benzimidazol-2-ylidene) have been prepared and characterized. In the crystal structures of 2a and 2b the aromatic π–π stacking interactions are observed.
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