Abstract

Two gold(I) mononuclear complexes have been prepared by reacting gold(I) tetrahydrothiophene with N, N′-di(2,6-methyl)phenylformamidine. The neutral complex [ N, N′-di(2,6-methyl)phenylformamidine)–gold(I) chloride (C 17H 20AuClN 2) ( 1), crystallizes in the triclinic group P 1 ¯ while the cationic [ N, N′-di(2,6-methyl)phenylformamidine](tetrahydrothiophene)–gold(I) (C 21H 28AuN 2S) ( 2) crystallizes with a nitrate anion in the monoclinic group P2(1)/ n. Both compounds are good starting materials for synthetic gold chemistry.

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