Two new inorganic–organic hybrid single pendant hexadecavanadate derivatives with bifunctional electrocatalytic activities

Abstract

Two new supramolecular assembly hexadecavanadate derivatives of H 2[Cd(phen) 3] 2{[Cd(H 2O)(phen) 2](V 16O 38Cl)}·2.5H 2O 1 (phen = 1,10′-phenanthroline) and H 2[Cd(bipy) 3][Cd(H 2O)(bipy) 2]{[Cd(H 2O)(bipy) 2](V 16O 38Cl)}·1.5H 2O 2 (bipy = 2,2′-bipyridine), have been prepared under mild hydrothermal conditions and structurally characterized by IR, XPS spectra, TG analyses and single-crystal X-ray diffraction. Compounds 1 and 2 are constructed from single pendant [CdL 2] (L = phen, 1 and L = bipy, 2) modified hexadecavanadates. The hybrids 1 and 2 were used as solid bulkmodifier to fabricate bulk-modified carbon paste electrodes (CPEs) ( 1-CPE and 2-CPE) by direct mixing. The electrochemical behaviors and electrocatalysis of 1-CPE and 2-CPE indicate bifunctional electrocatalytic activities toward both the oxidation and reduction of nitrite. Furthermore, their electrocatalytic activities toward the reduction of bromate and oxidation of ascorbic acid are also studied in 1 M H 2SO 4 aqueous solutions.