Abstract
Two new dinuclear MnII cluster‐based metal‐organic frameworks, namely [Mn2(L)(DMPU)3]n (1) and [Mn(L)0.5(4,4'‐bipy)0.5(H2O)]n (2) (H4L = biphenyl‐3,3',5,5'‐tetracarboxylic acid, DMPU = 1,3‐dimethyltetrahydropyrimidin‐2(1H)‐one, 4,4'‐bipy = 4,4'‐bipyridine), were solvothermally synthesized and characterized by single‐crystal X‐ray diffraction, powder X‐ray diffraction, and magnetic studies. Compound 1 crystallizes in the monoclinic P21/n space group and displays a 3D framework with 4‐connected crb/BCT‐type topology, and compound 2 crystallizes in the monoclinic C2/c space group and displays a 3D framework with (4,6)‐connected sqc422‐type topology. The magnetic studies of compounds 1 and 2 show the presence of weak antiferromagnetic interactions within the dinuclear MnII units.
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