Abstract
Two new CuII coordination polymers with bis-imidazole ligand, bitrb, were synthesized and characterized. Reaction of CuSO4·5H2O with bitrb in a MeOH-H2O mixed solution produced a 2D coordination polymer, while a similar reaction in a THF-MeOH mixed solution gave a 1D coordination polymer. The former compound converts to the latter in a THF-MeOH mixed solvent, while the reversed reaction proceeds in MeOH-H2O media. Their crystal structures and the reversible transformations depending on the present solvents are described.
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