Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic Magnetic Refrigeration and Slow Magnetic Relaxation

Abstract

Two isostructural lanthanide-based 3D coordination networks [Ln = Gd(3+) (1), Dy(3+)(2)] with densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic characterization reveals that complex 1 shows a significant cryogenic magnetocaloric effect (-ΔSm = 44 J kg(-1) K(-1)), whereas 2 shows slow relaxation of magnetization.