Abstract
It has been found that pyridinium- and isoquinoliniumthiocarbamoylazomethinylides react with esters of acetylenedicarboxylic and propiolic acids in two directions. The first direction is heterocyclization of the thioamide fragment of the ylide; under the influence of dimethyl acetylenedicarboxylate, a thiazolyl-4-one ring is formed, and by the interaction of the pyridiniumylide with methyl propiolate, a thiazin-4-one ring is formed. The second direction consists of annelation of the imidazole ring to the isoquinoline system upon reaction with methyl propiolate.
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