Abstract
Competition between electron transfer via a through σ-bond and a through π-bond mechanism has been studied in 1-(4-cyanophenyl)-4-(cyanomethylene)piperidine. In this trichromophoric system designed in a configuration acceptor−donor−acceptor, where the donor chromophore is part of the initially excited state, electron transfer occurs in two directions. The results of the single-photon-timing measurements indicate that, in both diethyl ether and acetonitrile, two charge-transfer states, a σCT and a πCT state, are formed, by transferring the electron through the σ- or π-bonds, respectively. Information on the excited-state kinetics is obtained by means of global compartmental analysis of the fluorescence decay surface in acetonitrile. Both the σCT and πCT state are formed immediately upon excitation, within the time resolution of the experimental setup, and an electron exchange between the two polar states occurs at least in one direction.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.