Abstract
The compounds Re 2(DPhF) 3Cl 3 and Re 2(DPhF) 2Cl 4 have been prepared and structurally characterized (DPhF = anion of N, N-diphenylformamidine). The former has three bridging DPhF ligands, two equatorial Cl ligands and one axial Cl ligand. The Re–Re distances in two different crystallographic forms are 2.2318(8) Å and 2.2288(9) Å. The second compound has two trans DPhF ligands and the Re 2Cl 4 unit is planar with Re–Re = 2.177(1) Å, Re–Cl(av) = 2.319(5) Å, Re–N(av) = 2.06(1) Å and Cl–Re–Cl(av) = 106.0(1)°.
Published Version
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