Abstract
Self-assembled monolayer anthraquinone-polyethers on gold electrodes were prepared and characterized by various spectroscopic and electrochemical techniques. The monolayers exhibited better thermal stability in solution, suggesting that multianchoring effects of disulfide moieties improve the integrated adhesion and binding stability of the monolayers. In contrast to solution electrochemistry, the unique structure and packing of the monolayer lead to selective ion binding to ions with the right size and charge, such as potassium and sodium.
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