Abstract

Two-dimensional-growth small molecular organic thin film with high quality is fabricated by ultrasonic spray coating technology (USC) from the toluene solution of 4,4′,4″-tris (carbazol-9-yl) triphenylamine (TCTA). In comparison to the vacuum thermal evaporation (VTE) TCTA film, the USC-TCTA film obtained from liquid-phase solution possesses more uniform surface topography. The differences between the USC-TCTA and the VTE-TCTA in optical property, electrical property and formation mechanism are also studied in detail. Besides, to evaluate the hole transport and electron blocking ability of USC-TCTA film, the organic light-emitting devices (OLEDs) employing USC-TCTA film as hole transport layer are fabricated successfully. Additionally, the green OLEDs based on USC-TCTA film perform as well as the ones with VTE-TCTA film in current density, luminance, efficiency and color stability, and show even better tolerance to high bias voltage.

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