Abstract

We present measurements of electron stimulated desorption (ESD) yields of D −, obtained from sub-monolayer amounts of C 2D 6 physisorbed on rare gas substrates; the latter consisting of alternating layers of Xe and Kr adsorbed at 20 K on Pt. Negatively charged excitons (NCE), for example, Xe∗ − or Kr∗ −, which are produced by electron impact, may couple to dissociative anion states of C 2D 6, resulting in sharp resonance enhancements in the D − ESD yields. Our measurements suggest that resonant diffusion of the Xe NCEs can be restricted to a single Xe layer, by placing a Kr multilayer spacer between the Xe and the metal substrate. This is attributed to the 1.85 eV insulating band-gap difference at the XeKr interface.

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