Abstract
The first electronic excitation and adiabatic ionization energies of 35Cl and 37Cl 4-chlorostyrene were similar, with values of 33,977±2 and 67,972±5cm−1, respectively. The general features in the obtained vibronic and cation spectra of the two isotopologues were similar. A frequency shift of 1–5cm−1 was observed on many active vibrations of the 35Cl and 37Cl isotopologues of 4-chlorostyrene in the S1 and D0 states. This frequency difference at each mode may reflect the degree of Cl atom involvement in the overall vibration.
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