Abstract
AbstractA multielectron theory of exchange interactions in transition metal ion pairs in cubic matrices and ions in orbitally degenerate states is developed. The orbitally dependent part of the exchange Hamiltonian is expressed by Pauli operators determined in the orbital space for the case of an orbital doublet and by fictitious orbital operators L̃ = 1 in the case of a triplet state. It is shown that the anisotropic exchange parameters may be estimated from isotropic ones. The theory described is compared with experiment.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
