Abstract
Calcium-based metal–organic frameworks (Ca-MOFs) with room-temperature phosphorescence (RTP) properties are promising for applications. Herein, two 3D Ca-MOFs with robust RTP have been successfully synthesized with scaled-up production. The afterglows of these two Ca-MOFs are visible to the naked eye in darkness that lasts for approximately 13 s once they are excited with 365 nm UV light. It is mainly attributed to the rigid and dense structures of 3D Ca-MOFs via 4,5-Imidazole dicarboxylic acid tugging Ca2+ elucidated by means of single-crystal X-ray diffraction and density functional theory (DFT). Furthermore, a program was designed for dynamic anti-counterfeiting based on the long afterglow properties of Ca-MOFs, which can be extended for all kinds of material with long afterglow.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
