Abstract
Based on flexible ligands 4,4′-((5-carboxy-1,3-phenylene)bis(oxy))dibenzoic acid (H3cpbda), two flexible N-donor ligands with the similar molecular length, 3-bis(1H-imidazol −1-yl)propane (bip) and 1,3-bis(pyridin-4-yl)propane (bpp), were introduced to assemble MOFs with different metals. Two 2D-MOFs, [Cd1.5(cpbda)(bip)0.5(H2O)]n (1) and [Cu(Hcpbda)(bpp)(H2O)]n (2), were successfully synthesized and characterized by single-crystal X-ray diffraction, power X-ray diffraction, thermal-gravimetric analysis and fluorescence spectroscopy. The different terminal functional groups (imidazole and pyridine) in bip and bpp ligands generate different molecular coordination angels, which show diverse terminal type and bridged type in two 2D structures. The sensing results of 1 on metal cations and anions and magnetic property of 2 were studied. The influences of various N-donor ligands in assembly of flexible MOFs accompany with H3cpbda are also summarized.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
