Abstract
4,5-Bis(aminomethyl)acridine (LN) was investigated as a chemosensor for metal ions in aqueous solutions and it is selective for Zn2+, through a linear fluorescence enhancement of 230% in the concentration range of 17.8–600 μmol L−1. Benesi-Hildebrand and Job method formalisms showed the formation of a very stable complex with one of the highest binding constant (2.43 × 1014 L2 mol−2) reported for zinc, and a 2:1 (metal ion/sensor) ratio. DFT and TD-DFT calculations could explain the fluorescence augmentation upon complexation between Zn2+ and LN. Limit of detection and limit of quantification (R2 = 0.9970, least squares method) were found to be 5.36 and 17.8 μmol L−1, respectively, and appropriate robustness was verified based on the variation of several analytical conditions. Practical application testes showed recovery results such as (92 ± 4)% (tap water) and (99 ± 1%) (mineral water), proving to be adequate to quantify Zn2+ in real water samples, showing no effect of interfering ions.
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