Turning Trash to Treasure: The Influence of Carbon Waste Source on the Photothermal Behaviour of Plasmonic Titanium Carbide Interfaces.

Abstract

Pyrolysis of carbonaceous waste materials has emerged as an effective recycling method to generate value-added products. In addition to producing pyrolytic oil and gas, the thermal degradation process yields solid pyrolytic char, which can be further processed. In this study, local waste materials, birch wood residue, Japanese knotweed stems, spent coffee grounds, tire rubber, and lobster shells were assessed for their potential to form pyrolytic char. After a simple acid treatment, many of these chars were successfully incorporated into solid-state synthesis of plasmonic titanium carbide (TiC) nanoparticles (NPs). Each char exhibited unique physical and chemical properties, which were leveraged to synthesize TiC NPs with distinct characteristics. To evaluate the plasmonic behavior of these TiC samples, solar-driven desalination experiments were performed. Notably, TiC derived from tire rubber demonstrated a high broadband absorbance and achieved a solar-to-vapor generation efficiency of 95%, corresponding to an evaporation rate of 1.40 ± 0.01 kg m-2 h-1 under one-sun illumination. This performance is the highest among all chars tested and ranks among the top reported values in the literature. Additionally, the evaporation interface maintained its performance over multiple cycles and under highly hypersaline conditions.