Abstract
An extremely stable pillar-layered metal-organic framework (MOF), [Cd4(NDC)3(4-Hptz)2(H2O)2]·H2O (1), has been successfully designed and synthesized (4-Hptz = 5-(4-pyridyl)-tetrazolate, NDC = 1,4-Naphthalenedicarboxylic acid). Compound 1 can detect Cr3+ in water by fluorescence enhancement, which is the first known case of MOF. This is of great significance for our study on new fluorescent probes.
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