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Abstract
A pair of framework-catenation isomers (UPC-19 and UPC-20) based on an anthracene-functionality dicarboxylate ligand were synthesized and characterized for the first time through tuning of the dimensionality of interpenetration. The interpenetration dimensionality significantly influences the properties including the porosity, gas-uptake capacity, and fluorescent sensing ability: UPC-19 with 5-fold interpenetration is nonporous, whereas the 3-fold interpenetration form of UPC-20 is porous and exhibits selective adsorption of CO2 and fluorescent sensing of Cu(2+) and Fe(3+) through fluorescence quenching.
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