Abstract
Presented here are two new luminescent Zn(II) coordination polymers, [Zn3(pdc)3(Hmtz)]n (1) and [Zn3(ntd)(mtz)4(DMA)2]n (2) (H2pdc=terephthalic acid, H2ntd=2,6-naphthalenedicarboxylic acid, Hmtz=5-methyl-1H-tetrazole). Single crystal X-ray diffraction analysis reveals that compound 1 features a 8-connected hex topological framework with the schläfli symbol of {36.418.53.6}, while compound 2 features a (3,4)-connected tfi topological framework with the schläfli symbol of {62.84}{62.8}2. The thermal stabilities and luminescent properties of 1–2 were also investigated.
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