Abstract

The reactions of Me 2 N 15 NH 2 with the tungsten hexafluoride or oxide tetrafluoride in the presence of NEt 3 in acetonitrile solution have been investigated by multinuclear NMR spectroscopy. The formation of the hydrazido(2-) complex [WOF 5 (NNMe 2 )] - and of the complex [WF 4 (NNMe 2 )(NHNMe 2 )] - containing both hydrazido(1-) and hydrazido(2-) ligands was observed

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