Abstract

High-resolution vacuum ultraviolet fluorescence excitation spectra of the D(O+u) ion-pair state of I2 have been obtained using a pulsed supersonic jet. Tunable vacuum ultraviolet radiation in the region 184–200 nm was produced by Raman shifting (fifth and sixth anti-Stokes) the output from a tunable excimer pumped dye laser. Vibrational constants valid up to v′=201 in the D(O+u) state have been determined.

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