Abstract
Dipoles in ferroelectric copolymer P(VDF-TrFE) can be driven by electric field, introducing phonon transport modulations via polarizing molecular chains. The thermal conductivity in single 75/25 P(VDF-TrFE) nanofibers is found to increase with electric field related phonon renormalization, resulted from change in vibrational assignment excited by polarization process. This is evidenced by a direct change of bond energy and bond length in 75/25 P(VDF-TrFE) nanofibers from Raman characterization under polarization electric field. The experimental results provide further intuitive evidences that the size of ferroelectric polymers could directly affect the ferroelectricity from the size-dependent thermal transport measurement.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
