Tunable magnetic properties and magnetic domain structure of nanocomposite permanent materials via Ti addition into Nd-Fe-Co-B alloys

Abstract

In this work, the effect of tunable Ti content on the microstructure, magnetic domain structure, and magnetic properties of as-spun and annealed Nd9.5Fe79-xCo5TixB6.5(x = 0,1,2,3,4) alloys at the quench speed of 18 m/s were investigated. For the as-spun alloy, augmenting the Ti content enhanced the initial crystallization temperature and the stability of the amorphous phase. Simultaneously, the incorporation of Ti led to augmentation in the quantity of nanocrystals within the amorphous matrix, thereby facilitating the formation of vortex-like magnetic domains with large size but reduced the saturation magnetization Ms. For the annealed alloy, the incorporation of Ti inhibited the precipitation of α-Fe phase, refined the grain, enhanced the exchange coupling between the soft and hard magnetic phase and facilitated the formation of smaller, more uniform vortex-like magnetic domains, These alterations were beneficial to improve the comprehensive magnetic properties. Furthermore, the addition of tunable Ti resulted in a remarkable impact on coercivity enhancement. The coercivity value exhibited a significant increase of 54.30%, surging from 374.24 kA/m to 577.51 kA/m. Upon a thorough analysis of the magnetic domains and coercive force mechanisms, it was ascertained that the introduction of Ti substantially augmented the creation of vortex-like domains. These domains effectively impede domain motion, consequently elevating the material's coercivity.