Tunable emission of single-phased NaY(WO4)2:Sm3+ phosphor based on energy transfer

Abstract

A series of NaY(WO4)2:Sm3+ phosphors were prepared by high temperature solid state reaction. When excited by ultraviolet and blue light, their emission spectra cover entirely visible light region, due to intrinsic luminescence of WO42- group as well as Sm3+ 4f-4f transitions. White light emission was obtained from NaY0.99Sm0.01(WO4)2 phosphor under radiation of 265nm UV light, and intense yellow and red emission from 6HJ(J=5/2, 7/2, 9/2) transitions were observed when pumped Sm3+ 4G5/2 by 405nm blue light. With incorporation of Sm3+ into NaY(WO4)2 host, higher-level emission from Sm3+ at 650nm was generated by energy transfer from WO42- to Sm3+ under excitation of 265nm. The corresponding energy transfer mechanism was demonstrated to be a dipole-dipole interaction. In addition, tunable emission from blue to white and, finally, to red was realized by increasing Sm3+ doping concentration. The band gap of NaY(WO4)2 calculated from diffuse reflection spectra indicates a semiconducting character. All these results show that NaY1−xSmx(WO4)2 phosphor provides promising application for conversion of frequencies emitted by UV or blue LEDs.