Tunable Dipole Surface Plasmon Resonances of Silver Nanoparticles by Cladding Dielectric Layers.

Abstract

The tunability of surface plasmon resonance can enable the highest degree of localised surface plasmon enhancement to be achieved, based on the emitting or absorbing wavelength. In this article, tunable dipole surface plasmon resonances of Ag nanoparticles (NPs) are realized by modification of the SiO2 dielectric layer thicknesses. SiO2 layers both beneath and over the Ag NPs affected the resonance wavelengths of local surface plasmons (LSPs). By adjusting the SiO2 thickness beneath the Ag NPs from 5 nm to 20 nm, the dipole surface plasmon resonances shifted from 470 nm to 410 nm. Meanwhile, after sandwiching the Ag NPs by growing SiO2 before NPs fabrication and then overcoating the NPs with various SiO2 thicknesses from 5 nm to 20 nm, the dipole surface plasmon resonances changed from 450 nm to 490 nm. The SiO2 cladding dielectric layer can tune the Ag NP surface charge, leading to a change in the effective permittivity of the surrounding medium, and thus to a blueshift or redshift of the resonance wavelength. Also, the quadrupole plasmon resonances were suppressed by the SiO2 cladding layer because the dielectric SiO2 can suppress level splitting of surface plasmon resonances caused by the Ag NP coupling effect.