Abstract
Resume Gas-liquid chromatographic determination of equilibrium constants of interactions between solutes and free nitrile groups The equilibrium constants of interactions between some solutes and free nitrile groups isolated in the methylene matrix have been determined by gas-liquid chromatography. These constants take into account the molar volumes of solutes and of two mixed liquid stationary phases (squalane and stearonitrile). These interactions have been characterized to be of the dipole-dipole type.
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