Tubular Sediment-Water Electrolytic Fuel Cell for Dual-Phase Hexavalent Chromium Reduction.

Abstract

A novel tubular sediment-water electrolytic fuel cell (SWEFC) was fabricated for the reduction of Cr(VI) in a dual-phase system. The approach simulates a standing water body with Cr(VI)-contaminated overlying water (electrolyte) and bottom sediment phase with electrodes placed in both the phases, supplemented with urea as a potential electron donor. Cr(VI) reduction efficiency of 93.2 ± 1.3% from electrolyte (in 1.5h) and 81.2 ± 1.3% from the sediment phase (in 8h) with an initial Cr(VI) concentration of 1,000mg/L was observed in a single-cell configuration. The effect of initial Cr(VI) concentration, variation in sediment salinity and pH, and different electron donors on the SWEFC performance were systematically investigated. SWEFC showed enhanced performance with 2.4-fold higher current (193.9mA) at 400mg/L Cr(VI) concentration when cow dung was used as a low-cost alternative to urea as an electron donor. Furthermore, reactor scalability studies were carried out with nine-anode and nine-cathode configuration (3 L electrolyte and 2kg sediment), and reduction efficiencies of 98.9 ± 0.9% (in 1h) and 97.6 ± 2.2% (in 8h) were observed from the electrolyte and sediment phases, respectively. The proposed sediment-water electrolytic fuel cell can be an advanced and environmentally benign strategy for Cr(VI) remediation from contaminated sediment-water interfaces along with electricity generation.