Abstract
By using a 1,3-alternate conformation of calix[4]arene tetrabenzoic acid (H4CTB), a pair of 4,4′-bipyridine has been aligned forming a cocrystallized one-dimensional tubular product 1. Inspired by this result, the 1,3-alternate H4CTB has been utilized as “clips” to anchor the C═C bond pairs of 4,4′-bipyridylethene to give an isotypical H-bonded tubular product 2 which undergoes the solid-state photodimerization.
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