TRU utilization and MA transmutation in thorium-based fluorinated molten salt fast reactor

Abstract

In this paper, a thorium-based fluorinated molten salt fast neutron reactor is taken as the research object, and the utilization of thorium resources, reuse of transuranic waste (TRU), and transmutation of minor actinide (MA) in fast reactor are the research purpose. The fast reactor adopts a multi-layer core structure, in which the fuel is divided into an inner fission fuel zone and an outer breeding fuel layer, respectively loaded with fluorinated molten salts LiF+ThF4+XF4 (where X is 233U, TRU, or 233U+MA) and LiF+ThF4. In addition to serving as nuclear fuel, these two molten salts also act as coolants in the primary circuits.Through the cross sections of nuclear reactions, transmutation chain of actinide nuclides, and the particle population density formula of actinide nuclides in nuclear reaction equilibrium, the possible nuclear reactions of actinide nuclides in thorium-based fast reactors are analyzed. The calculated results show that the thorium-based fast reactor has the following characteristics: fast neutron energy spectrum, negative temperature reactivity coefficient, effective utilization of thorium resources, the ability to breed fissle fuel such as 233U, production of high-purity radioisotope 238Pu material, and the ability to incinerate Pu and MAs in the TRU spent fuel.In the 233U fuel scheme, the 233U fuel is breeded, breeding ratio of fissile fuels is 1.21, the reaction products contain very little Np, and almost no Pu, Am, and Cm long-lived radionuclides. In the TRU fuel scheme, the annual capacity to incinerate MAs and Pu is 1072.6 kg, while producing a large amount of 233U and 233Pa fuel (together 1162.5 kg/year).In the 233U+2.0 wt% TRU-MAs fuel scheme, 127.35 kg of MA waste can be incinerated annually, and their transmutation rate is 15.95%, which is equivalent to the annual production of MA nuclear waste from 4.9 conventional 1000 MWe light water reactors. Here, TRU-MAs is the mixtured MA fuels after separation of Pu from the TRU fuel. At the same time, radioactive fuel 238Pu, which can be used for space nuclear power, is produced with an annual yield of 87.89 kg and an isotopic abundance of 87.57%. If the added TRU-MAs fuel is replaced with 2.0 wt% 237Np fluorinated salt, the annual yield and isotope abundance of 238Pu are further increased to 130.24 kg and 95.4%.