Abstract
Tris(trimethylsilyl)methane has excellent properties for an internal chemical shift thermometer to measure temperatures in 13C DNMR spectroscopy [Δδ between the 13C signals of Si(CH3)3 and CH carbons]. It is chemically inert, soluble in most organic solvents and has an almost linear dependence of Δδ on temperature. The sensitivity (approximately 1°C Hz-1 at 90 MHz) allows the measurement of temperature to within 1°C. The chemical shift is solvent dependent, so each solvent mixture must be calibrated. Calibrations are presented for seven solvents. © 1998 John Wiley & Sons, Ltd.
Submitted Version
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
