Trissarcosine barium(2 + ) dibromide—a new complex of N‐methylglycine

Abstract

AbstractWe obtained a new complex containing sarcosine (CH3NH2+CH2COO−) and barium(2 + ) dibromide (TSBB) in 3:1 molar ratio, as well as its deuterated analog. Single‐crystal X‐ray diffraction measurements show that TSBB crystallizes in the monoclinic system, space group P2(1)/c. The unit cell parameters are as follows: a = 18.345(4) Å, b = 10.668(2) Å, c = 8.9212(18) Å, β = 91.86(3)°, and Z = 4. The structure was determined with final R1 = 0.0396 (for I > 2σI). The crystal possesses a pseudohexagonal symmetry down c axis showing the resemblance to the crystal structure of trissarcosine calcium chloride (TSCC). There are NHBr hydrogen bonds (HB) of six types. TSBB crystal undergoes a phase transition at 416 K (heating)–415 K (cooling) of continuous nature. The spectroscopic [Infrared (IR) and Raman] investigation of the crystal was performed at room temperature. The results are discussed with respect to the crystallographic data, as well as the results obtained for TSCC crystal. Copyright © 2008 John Wiley & Sons, Ltd.