Abstract
In the title compound, [Fe(C12H10N2O)3](ClO4)2, the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octahedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Intermolecular O—H⋯O hydrogen bonds between the hydroxyl groups of the cation and the counter-anions form an infinite one-dimensional chain in the c-axis direction.
Highlights
In the title compound, [Fe(C12H10N2O)3](ClO4)2, the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octahedral coordination geometry, with overall formation of the meridional (OC-621) isomer
Symmetry codes: (i) −x+1, y+3/2, −z+1/2; (ii) −x+1, −y, −z; (iii) −x, y+1/2, −z+1/2
Summary
R factor = 0.062; wR factor = 0.115; data-to-parameter ratio = 15.6. In the title compound, [Fe(C12H10N2O)3](ClO4), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octahedral coordination geometry, with overall formation of the meridional (OC-621) isomer. Intermolecular O—H O hydrogen bonds between the hydroxyl groups of the cation and the counteranions form an infinite one-dimensional chain in the c-axis direction.
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