Abstract
In the crystal structure of the title compound, [Cu3Br3(C26H24P2)3]·0.5CH3COCH3, two of the Cu centers are bridged by two bromide anions forming a Cu(μ-Br)2Cu core, which is further bridged by a 1,2-bis(diphenylphosphino)ethane (dppe) ligand. The third Cu center is terminally bound to another bromide ligand and is connected to the other two Cu atoms by bridging dppe ligands, forming a triangular cluster unit. The acetone solvent molecule exhibits twofold disorder about an inversion centre at (, 1, 0). The crystal structure is stabilized by intermolecular C—H⋯Br hydrogen bonds.
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More From: Acta Crystallographica Section E Structure Reports Online
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