Abstract

Tris[(pyridin-4-yl)methyl]phosphine and its P-oxide, new promising ligands, were obtained based on the reaction between 4-[(trimethylsilyl)methyl]pyridine and PCl3. The coordination properties of tris[(pyridin-4-yl)methyl]phosphine oxide (L) were exemplified by the synthesis of a braided-shaped chain polymer [Cu4I4L2] showing green luminescence at ambient temperature.

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