Abstract
The crystallization behavior of the title compound, [Co(C2H8N2)3](C2O4)(ClO4)·2H2O, has been studied in order to evaluate the effect of the counter-anion on the crystalline structures of [Co(en)3](C2O4)·X (en = ethylenediamine). Two-dimensional intermolecular hydrogen-bonding networks are formed between the amine protons of the [Co(en)3]3+ cations and the O atoms of the oxalate anions. Perchlorate and water molecules fill in the channels between the two-dimensional networks and form hydrogen-bonding interactions with the two-dimensional layers, thus constructing a three-dimensional hydrogen-bonding network.
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