Abstract
In the cation of the title compound, [Co(C2H8N2)3][In(C2O4)3(H2O)], the CoIII atom is coordinated by six N atoms from three ethylenediamine molecules. The CoIII—N bond lengths lie in the range 1.956 (4)–1.986 (4) Å. In the anion, the InIII atom is seven-coordinated by six O atoms from three oxalate ligands and by a water molecule. The cations and anions are linked by extensive O—H⋯O and N—H⋯O hydrogen bonds, forming a supermolecular network.
Highlights
In the cation of the title compound, [Co(C2H8N2)3][In(C2O4)3(H2O)], the CoIII atom is coordinated by six N atoms from three ethylenediamine molecules
The InIII atom is seven-coordinated by six O atoms from three oxalate ligands and by a water molecule
The cations and anions are linked by extensive O—HÁ Á ÁO and N—HÁ Á ÁO hydrogen bonds, forming a supermolecular network
Summary
In the cation of the title compound, [Co(C2H8N2)3][In(C2O4)3(H2O)], the CoIII atom is coordinated by six N atoms from three ethylenediamine molecules. The CoIII—N bond lengths lie in the range 1.956 (4)–1.986 (4) A. The InIII atom is seven-coordinated by six O atoms from three oxalate ligands and by a water molecule. The cations and anions are linked by extensive O—HÁ Á ÁO and N—HÁ Á ÁO hydrogen bonds, forming a supermolecular network. Related literature For metal phosphates and germanates templated by metal complexes, see: Du et al (2004); Pan et al (2005, 2008); Wang et al (2003a,b,c). For coordination polymers templated by metal complexes, see: Pan et al (2010a,b, 2011), Tong & Pan (2011)
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