Abstract
The structure of the first nickel coordination complex with 1,10-phenanthroline (phen) containing thiourea as a cocrystallization molecule is reported. The title compound, [Ni(C 12 H 8 N 2 ) 3 ](NO 3 ) 2 .CH 4 N 2 S.H 2 O, crystallizes in the centrosymmetric space group C2/c. The crystal structure is formed by [Ni(phen) 3 ] 2+ cations, water and thiourea molecules positioned on a twofold axis, with the nitrate anions in general positions. The packing is directed by electrostatic interactions, stacking of phen molecules and hydrogen bonds between the crystallization molecules and the nitrate anions.
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More From: Acta Crystallographica Section C Crystal Structure Communications
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