Abstract

The title compound, Rb3CoCl4NO3, is isostructural with K3ZnCl4NO3. It is built up from Rb+ cations, NO3− anions and [CoCl4]2− complex ions which form a layer-like arrangement: one layer contains only rubidium cations while the other contains a mixture of rubidium, nitrate and tetra­chloro­cobaltate ions. Both rubidium cations are ninefold coord­inated by three O atoms and six Cl ions. One Rb atom, the Co atom, two Cl atoms, the N atom and one O atom lie on a crystallographic mirror plane.

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