Abstract
Triplet-state benzophenone rapidly sensitized the photoreduction of Cu(acac)2 in alcohols to give polymeric Cu(acac) as black precipitates. The binary complexes of Cu(acac) of polypyridines, polysulfide, olefins, acetylenes, and carbon monoxide could be generated in solution under an inert atmosphere when a ligand was present insitu during photoreduction or added after an appropriate photoreduction was completed. Except Cu(acac)—(PPh3)2, the Cu(acac) complexes of various ligands are sensitive to air oxidation, but show a wide range of reactivity towards disproportionation and photolysis. In the presence of terminal acetylenes, amorphous copper(I) acetylides were isolated in good yields.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.