Abstract

Directly linked bisporphyrin, Zn(II)2 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-2-(10,15,20-tris(3,5-di-tert-butylphenyl)porphyrin-5-yl)porphyrin, was investigated on the basis of the magnetic property of its bis(pi-radical cation). A stable triplet state of the bis(pi-radical cation) of the bisporphyrin, which obeys the Curie law, was successfully observed.

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