Triple oxygen and hydrogen isotopes of glacial diamictites record crustal maturation and changing surface conditions through geologic time

Abstract

The triple oxygen and hydrogen stable isotopic compositions of 24 glacial diamictite composites with depositional ages from 2.9 to 0.3 Ga are used to reconstruct the evolution of the continental crust and surface environments. The δ18O of the diamictite composites increases from the Archean to the Phanerozoic by ~4 ‰ (3–5 ‰ in Mesoarchean to 13.5 ‰ in Neoproterozoic), a trend that is comparable to those seen in shales and granites, although the diamictites plot on the lower δ18O end of the range seen in shales. The Δ’17O0.528 decreases from −0.04 to −0.15 ‰, overlapping with shales and granites. Nine zircon separates extracted from individual diamictites also show a ~3 ‰ increase in δ18O from 3.75 to 4.5 ‰ to 7 ‰ between 2.9 and 0.6 Ga. The δ18O of diamictites and zircon separates negatively correlates with ɛNd(i) of the diamictites, suggesting that the longer the rocks reside in the upper continental crust (the lower the ɛNd), the more they are subjected to repeated weathering cycles, thus acquiring a higher δ18O and lower Δ’17O0.528 during each cycle. On a triple O isotope plot (δ17O vs δ18O), diamictites define an array with a slope of 0.523, analogous to granites and shales.The δD values of nearly all diamictites overlap with the typical mantle and crustal ranges of −58 ± 12 ‰ and − 69 ± 24 ‰, respectively, but are on the lower end of coeval shale values. Water, contained primarily in sheet silicates, ranges from 2.85 wt% (pre-2.4 Ga) and 2.35 wt% (post-2.4 Ga), showing no temporal change. The youngest diamictites (0.3 Ga Dwyka Group) exhibit low δD values of −105 to −111 ‰, lower than the typical crustal values, potentially reflecting the near-polar position of South Africa at the time of their deposition, which is corroborated by the reconstructed δ18O value of −26 ‰ based on triple oxygen isotopic systematics.The chemical index of alteration (CIA) allows inverting measured δ18O and Δ’17O values of diamictite composites into a pure weathering product (wp) end member by subtracting values of coeval unweathered crust based on tzircon δ18O. This reveals that the δ18Owp also increases with time, suggesting that the increase in δ18O (decrease in Δ’17O) of the maturing crust is insufficient to fully explain the trends. Therefore, at least part of the increasing δ18Owp likely reflects increasing δ18O of the hydrosphere. Reconstructed surface temperatures around the time of diamictite deposition using δ18Owp and Δ’17Owp display a general decrease since the Archean. Given the diagenetic and post-diagenetic history experienced by the diamictites, the temporal and global trends should be interpreted with caution. Nonetheless, reconstructed δ18Owater shows an increase from −21 ‰ at 2.9 Ga to −11 ‰ at 0.6 Ga. Thus, diamictites, like shales, broadly monitor the evolution of surface conditions on Earth from warmer to colder and from lower to higher δ18Owater values of the hydrosphere.