Abstract
Some corrections have been made to the mathematical method which is used for evaluating conductivity data in solvents of low dielectric constant where triple ion equilibria are present and ionic interactions are appreciable. In acetic acid the triple ion equilibrium constant of sodium perchlorate, which has been estimated from a limiting mobility based on the relative sizes of the ions and triple ions, agrees with that calculated from the equation of Fuoss and Kraus1 for the triple ion equilibrium constant. The limiting mobility of the perchloric acid triple ion electrolyte is greater than that estimated from the relative sizes of the ions and arises from the operation of a proton jumping mechanism.
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