Abstract

Oxidative-addition reactions of triphenylpnictogens, Ph 3M (M = N, P, As, Sb, Bi), with selenium(IV) oxide, sulphur dichloride, disulphur dichloride, diselenium dichloride, lead(IV) acetate and potassium selenocyanate have been studied. Mass spectra are described of Ph 3M (M = N, P, As, Sb, Bi), Ph 3MO (M = P, As), Ph 3MS (M = P, As, Sb), Ph 3PSe, Ph 3Sb(OH) 2 and Ph 3M(OCOCH 3) 2 (M = Sb, Bi).

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