Abstract
Two differently substituted pyrazole ligands have been investigated with regard to the topology of their Pt complexes: upon deprotonation, two mononuclear 1:2 PtII-pyrazole complexes—one of the sterically unhindered 4-Me-pzH and one of the bulky 3,5-tBu-pzH (pzH = pyrazole)—yield the corresponding 1:2 PtII-pyrazolato species; the former a triangular, trinuclear metallacycle (1), and the latter a dinuclear, half-lantern species (2) formed via the unprecedented cyclometallation of a butyl group. Stoichiometric oxidation of the colorless PtII2 complex produces the deep-blue, metal–metal bonded PtIII2 analog (3) with a rarely encountered unsymmetrical coordination across the Pt-Pt bond. All three complexes have been characterized by single crystal X-ray structure determination, 1H-NMR, IR, and UV-vis-NIR spectroscopic methods. The XPS spectra of the PtII2 and PtIII2 species are also reported. Density functional theory calculations were carried out to investigate the electronic structure, spectroscopic properties, and chemical bonding of the new complexes. The calculated natural population analysis charges and Wiberg bonding indices indicate a weak σ-interaction in the case of 2 and a formal Pt-Pt single bond in 3.
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
